• Yang LIU , Genmao ZHOU , Ke LIU , Yong LI
    Uranium Mining and Metallurgy. 2025, 44(3): 28 -34.

    With the development of uranium mining, uranium mining technology has rapidly advanced, but various challenges have emerged. In the process of in-situ leaching of uranium, there is often a phenomenon of decreased pumping and injection volume, which seriously affects the efficiency of uranium leaching. In response to the problem of decreased pumping and injection volume, physical, chemical, and combined well cleaning techniques have been carried out. The washing technology can solve the blockage around the wells, but its washing effect lasts for a short time and has a small impact radius, which cannot fundamentally solve the problem of decreased flow rate. The liquid flow cavitation technology is widely used in petroleum extraction, which can effectively increase the production of pumping wells and reduce the pressure of injection wells. However, it has not been involved in the in-situ of uranium process. In this paper, by comparing the difference between uranium leaching technology and petroleum technology, the cavitation device is optimized, and the drilling wellhead device is improved in the ground test, and then the liquid flow cavitation test is carried out. During the test, the operation displacement reached 2 m3/min and the pressure was about 21 MPa, which verified the feasibility of liquid flow cavitation technology in in-situ of uranium, and provided a new idea for improving the permeability of uranium mine.

  • Liqian DAI , Chaohui ZHU , Yuan MIN
    Uranium Mining and Metallurgy. 2025, 44(3): 114 -122.

    The data of mineral resources reserves is the focus of the management of mineral resources reserves, and the national survey of mineral resources is a national and basic survey of mineral resources. Based on the national survey database of mineral resources in Henan Province, it is necessary to study and put forward a method to quickly update the resource reserve data in the mineral resources reserve database to facilitate the efficient use of the mineral resources management department, which is necessary to solve many problems such as data missing, error, redundancy and low timeliness in the reserve database and to better manage the mineral resources. By designing a computer program algorithm, the resource reserve data records in the national survey database of mineral resources and the mineral resource reserve database were automatically compared according to the relevant fields, and the differences were found. According to the differences, different program codes were adopted to update the resource reserve data in the reserve database. Compared with the method of manually updating data in daily reserves management, this method can update the resources and reserves data in the mineral resources and reserves database more comprehensively, quickly, efficiently and accurately.

  • Jiahong KANG , Jianguo DENG , Biao CAO , Huan LIU , Liuyin SHI , Zaidao LIU , Jun LIU , Yingcai WANG , Wentao MA
    Uranium Mining and Metallurgy. 2025, 44(3): 35 -40.

    Due to the change in ore properties of a certain hard rock uranium mine with the increase of mining depth, the heap leaching process of the ore encountered the problem of heap scaling. In order to solve the problem, the effects of leaching agent acidity, spray intensity, column height and particle size on heap scaling were studied. The results show that when the acidity of the leaching agent is 50.0 g/L, the spray intensity is 40.0 L/(m2·h), and the leaching period is 30 days, there is no scaling in the column leaching test, and the uranium leaching rate of -10 mm ore reaches 83.40%. The results of the 800 t ore pilot test confirms that there is no scaling in the heap with high acidity and large spray intensity, and the uranium leaching rate reaches 86.57%.

  • Xinlei MAO , Xiaoning YANG , Fei TENG
    Uranium Mining and Metallurgy. 2025, 44(3): 131 -135.

    The well washing process is an important way to increase the well water volume and increase the production capacity in the in-situ leaching uranium mine, but with the continuous improvement of safety and environmental protection requirements, the traditional well washing method alone can no longer meet the needs in recent years. A local leaching uranium mine has further improved the safety and environmental protection of the well washing process and the efficiency of the well washing process by carrying out the optimization and improvement of the safety and environmental protection of the well washing process such as the parallel well washing technology of the air compressor, the improvement of the acid adding method, and the recycling technology of the well washing wastewater, so as to maximize the effect of well washing, and ensure that the safety and environmental protection risks of the well washing process of the in-situ leaching uranium mine are controlled.

  • Mingbao LIU , Jiantao LI , Heng ZUO , Yunxiao LI , Guochao YAO , Jianli YAN , Wenfeng MA , Hongjian PANG , Tong ZHAO
    Uranium Mining and Metallurgy. 2025, 44(3): 50 -57.

    Taking the stone coal vanadium ore in Danfeng country, Shangluo city, Shannxi province as the research object, the vanadium leaching characteristics were studied using direct acid leaching and sulphuric acid-curing leaching process, respectively. The results indicate that the optimum vanadium leaching rate is 86.7% when using direct acid leaching process under conditions of sample fineness of 45%, H2SO4 concentration of 14%, leaching period of 6 h, leaching temperature of 80 ℃, Ca(ClO)2 dosages of 3%, CaF2 dosages of 2%, and the solid-liquid ratio of 1∶2. While the vanadium leaching rate can reach to 93.5% at ambient temperature by using sulphuric acid-curing leaching process under the conditions of sample fineness of 80%, H2SO4 dosages of 20%, wetting water dosages of 7.5%, curing temperature of 110 ℃, interval time of 10 h,water leaching period of 120 min, solid-liquid ratio of 1∶2. The results for sulphuric acid-curing leaching process is better than that for direct acid leaching process, and the conclusion can provide technical support for vanadium extraction from stone coal in Shannan region.

  • Chen ZHANG , Xianming HOU , Jiang HOU , Shaohai LI , Yuhui TIAN , Guang LI , Jia MA , Shouxun ZHANG
    Uranium Mining and Metallurgy. 2025, 44(3): 23 -27.

    The ore subjected to radioactive sorting treatment is crushed ore, with random shapes, which directly affects the accuracy of ore grade detection. To enhance the accuracy of radioactive separation detection, standard samples of uranium ore were prepared to conduct an influence test on how the shape of uranium ore affects detection efficiency. The relationship between the ore shape factor and the variation coefficient of detection efficiency was examined, leading to the establishment of a detection efficiency correction algorithm based on ore shape. Additionally, a quantification method for ore shape suitable for uranium ore radioactivity detection was proposed. The validity of the proposed detection efficiency correction algorithm has been verified through practical ore sorting tests. After implementing this algorithm, the error in uranium ore grade detection was reduced to less than 5% in over 70% of the test groups. This significantly mitigates the impact of ore shape on detection efficiency and enhances the accuracy of uranium ore grade detection.

  • Hongxing LI , Daiwen HOU , Yuan YUAN , Wensheng LIAO , Zhiming DU , Jinxun DENG
    Uranium Mining and Metallurgy. 2025, 44(3): 76 -81.

    The casing for in-situ leaching uranium needs to take into account the anti-corrosion performance and pressure resistance. In view of the complex geological conditions of dense sandstone uranium deposits, the performance of casing made of three materials, namely unplasticized polyvinyl chloride(UPVC), carbon steel and glass fiber reinforced plastic(GFRP), had been comparatively investigated. The results show that UPVC casing has good corrosion resistance but poor pressure resistance; carbon steel casing has good pressure resistance but is easy to corrode and has high cost; GFRP casing is excellent in corrosion resistance, pressure resistance and tensile strength. In terms of cementing quality, the cementing strength of GFRP casing, carbon steel casing and UPVC casing with cement is 1.80, 2.91 and 0.32 MPa respectively, and the cementing strength of GFRP casing with cement shows obvious advantages. GFRP casing is the best choice for in-situ leaching uranium in dense sandstone uranium deposits, which can meet the requirements of anti-corrosion performance and pressure resistance, and can guarantee the quality and service life of the drilling.

  • Yang GAO , Juan SUN , Xiaochao LIU , Yifu AN , Xuyang WU , Lijiang REN
    Uranium Mining and Metallurgy. 2025, 44(3): 68 -75.

    Alkaline materials were used to neutralize acidic waste residue. Open and closed experimental environments were set up with different dosing ratios and pH conditions.By monitoring the changes in pH, U, and $\mathrm{HCO}_{3}^{-}$ in the supernatant of the neutralization residue, and analyzing the mineral composition of the neutralization residue using XRD, the effect of CO2 on U stability during the neutralization process of acidic waste residue was studied. The results show that CO2 in the surrounding air during neutralization treatment affects the stability of pH and U in the neutralization residue. The fixation of CO2 by the neutralization residue under alkaline conditions is an acidification process. As the pH of the neutralization residue decreases, the CO2 fixed in the air transforms into $\mathrm{HCO}_{3}^{-}$, which gradually accumulates and causes the already stabilized U in the neutralization residue is leached out again. The pH adjustment experiment shows that there is no significant correlation between U and pH. The pH range for U leaching is 7.68~8.41, and $\mathrm{HCO}_{3}^{-}$ accumulates significantly in this range. There is a positive correlation between U and $\mathrm{HCO}_{3}^{-}$, with a correlation coefficient of 0.95. The production of $\mathrm{HCO}_{3}^{-}$ is a key factor affecting the stability of U in neutralization residue. When Ca(OH)2 is added excessively, secondary mineral CaCO3 will be generated in the neutralization residue. As CO2 is fixed, the pH of the neutralization residue decreases, and CaCO3 will partially dissolve and transform into $\mathrm{HCO}_{3}^{-}$. In the open experimental environment, only the 2.5% Ca(OH)2 experimental group and the 2.5% Mg(OH)2 experimental group maintain extremely low U leaching levels. After neutralization treatment, the pH of the neutralization residue is low, and very little CO2 is fixed in the air. $\mathrm{HCO}_{3}^{-}$ which affects U stabilityis hardly produced.

  • Zhaoshun HAN , Zhenzhong LIU , Chunguang LI , Yongmei LI , Kaixuan TAN , Yu ZHANG , Longcheng LIU
    Uranium Mining and Metallurgy. 2025, 44(3): 1 -15.

    Acidic wastewater generated by in-situ leaching uranium poses a serious threat to the groundwater environment. Aiming at the problems of long microbial remediation cycle, low survival rate and insufficient stability of electrokinetic remediation, a remediation method of microelectric field-coupled sulfate-reducing bacteria (SRB) was proposed. Through simulated wastewater remediation experiments, a three-chamber electrochemical device was constructed to explore the remediation mechanism and optimize the key parameters by combining the electromigration effect with the reduction function of SRB. The results show that the coupled remediation system significantly enhanced the uranium (VI) removal rate (more than 98%), and effectively reduced the concentrations of Ca, Mg, Al, Fe and other metal ions (removal rate>80%) and sulfate content (removal rate > 90%). Under the influence of an electric field, uranyl ions migrate to the cathode region, where they are predominantly reduced by S2- generated through the metabolic activity of sulfate-reducing bacteria (SRB) and subsequently co-precipitated. A minor fraction is reduced to U(IV) via electrode reactions. Experiments show that the different potential gradients can lead to different pH in the cathode chamber, which affects the remediation effect, with H+ leading to the escape of S2- under acidic conditions (pH<4) and the formation of soluble uranium complexes easily under alkaline conditions (pH>9); with a potential gradient of 0.2~0.4 V/cm, the balancing remediation efficiency, microbial activity and energy economy. This study provides a theoretical basis and technical support for the green and efficient remediation of acidic wastewater from uranium extraction by in-situ leaching technology.

  • Hui WANG , Di GAO , Yabin HUANG , Wangqiang KUANG , Shengting KUANG , Wuping LIAO
    Uranium Mining and Metallurgy. 2025, 44(3): 41 -49.

    The kinetics of thorium extraction from hydrochloric acid medium by a binary mixed system of di(2-ethylhexyl) (2-ethylhexyl)aminomethylphosphonate (Cextrant 230) and trialkylphosphine oxide (Cyanex 923) was investigated using the laminar flow constant interfacial cell method. For comparison, the kinetics of thorium extraction by the Cextrant 230 single system was also studied. Systematic investigations were conducted on the effects of stirring rate, temperature, specific interfacial area, extractant concentration, acidity, and chloride ion concentration on the extraction rate.The results show that the extraction regime is deduced to be chemical reaction-controlled for the sole Cextrant 230 system and diffusion-controlled for the mixture system, respectively, and the extraction reaction occurring at the bulk phase would be the rate-determining step. The thorium extraction rate is barely affected with temperature variations in the sole Cextrant 230 system, but increased in the mixture system, with an activation energy of 14.74 kJ/mol. The concentration of chloride and extractants linearly related to the extraction rate indicates that the extraction of Th4+ both in the sole Cextrant 230 system and mixture system is a pseudo first-order reversible reaction.

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